CO and CO2 Hydrogenation into Fuels and Chemicals in 3D Microreactors
Debasish. Kuila
Department of Chemistry and Applied Sciences and Technology, Joint School of Nanoscience and Nanoengineering, North Carolina A&T State University, Greensboro, NC 27411 dkuila@ncat.edu
Abstract: Catalytic conversion of biomass into fuels, chemical synthons and value-added chemicals using microchannel microreactors and tubular reactors is one of the main objectives at our NSF-CREST Bioenergy Center. In our previous studies, we investigated the use of silicon (Si) and 3-D printed stainless steel (SS) microreactor to understand metal-support interaction of different catalysts and their stabilities on formation of hydrocarbons at 1 atm and 20 bar.1-4 Mesoporous silica supported catalyst such as Co-Ru-KIT-6 exhibits a long-range ordered structure as evidenced by BET and lower-angle XRD studies, and yielded liquid fuel in SS the microreactor at 20 bar. 5 Our studies with Fe and Fe-Co catalysts have been extended to supports such as mixed SiO2-Al2O36 , graphene oxide (GO)7 and also in the presence of metal promoters. An overview of our ongoing studies on Direct Air Capture of CO2 (DAC) and development of catalysts for CO2 hydrogenation also in the presence of Non-thermal Plasma will be presented.
References: 1. R. Y. Abrokwah et al, Molecular Catalysis, 2019, 478, 110566. 2. N. Mohammad et al, (a) Catalysts 2019, 9, 872; 4; (b) Catalysis Today 2020; 358, 303-315. 3. S. Bepari et al., Applied Cat. A, 2020 (4), 608, 117838. 5) N. Mohammad et al, Catalysis Today, 2021, https://doi.org/10.1016/j.cattod.2021.09.038, 6) M. Arslan et al, Current Topics in Catalysis, 2023, 66:477–497 https://doi.org/10.1007/s11244-022-01733-z. 7) S. Hassan, et al, Int. J. Hydrogen Energy, 2024, 67, 1248-1261.
Biography: Debasish Kuila, previous Chair and Professor of chemistry, is the Research Director of NSF-CREST Bioenergy Center and the PI of the DOE-BES and DOE-EERE projects at North Carolina A&T. He is an affiliate of JSNN and an adjunct professor of Wake Forest School of Medicine. He spent over 14 years at Hoechst Celanese and Great Lakes Chemical Corporations, Purdue, and Louisiana Tech University. His research interest spans from materials/biomaterials, CO2 capture/conversion, plastics upcycling, cell biology on modified surfaces, to catalysis. He was the 2020 Senior Researcher of the CoST, and received 2019 Chemcon Distinguished Speaker Award at the International Conference on Energy & Environment, Jaipur, India.