Manuscripts currently under review or in press

  1. Wang, H.; Misra, S.; Wang, F.; Miller, G.J., "Crystal Structure and Magnetic Properties of Gd5GaxSi4-x," Inorg. Chem. 2009, submitted for publication.
  2. Thimmaiah, S.; Miller, G.J., "On the Structural Chemistry of Gamma-Brasses: Two Different Interpenetrating Networks in Ternary F-Cell Pd-Zn-Al Phases," Chem. Eur. J. 2009, submitted for publication.
  3. Paudyal, D.; Mudryk, Ya.; Pecharsky, V. K.; Misra, S.; Miller, G. J.; Gschneidner, Jr. K.A., "Controlling the Magnetism of Gd5Ge4 via Precise Chemical Substitution, J. Appl. Phys. (Conference Proceedings, 11th Joint MMM-Intermag Conference, January 18-22, 2010, Washington, DC).
  4. Thimmaiah, S.; Miller, G.J., "Pd2.28(1)Zn10.37(1)Al0.35(1), a ternary γ-brass type structure," Acta. Cryst., Section E, 2010, accepted for publication.
  5. Wang, F.; Pearson, K.N.; Miller, G.J., "EuAgxAl11-x with the BaHg11-Type Structure: Composition, Coloring, and Competition with the BaCd11-Type Structure," Chem. Mater. 2010, in press.


  1. Kim, S.-J.; Miller, G. J.; Corbett, J. D., "Zig-zag Chains of Alternating Atoms in A2AuBi (A = Na, K) and K2AuSb. Synthesis, Structure, and Bonding," Z. Anorg. Allg. Chem. 2010, 636, 67-73 .
  2. Li, B.; Kim, S.-J.; Miller, G. J.; Corbett, J. D., "K23Au12Sn9 - An Intermetallic Compound Containing a Large Gold-Tin Cluster. Synthesis, Structure, and Bonding," Inorg. Chem. 2010, 49, 1503-1509 .
  3. Li, B.; Kim, S.-J.; Miller, G.; Corbett, J., "Synthesis, Structure, and Bonding in K12Au21Sn4. A Polar Intermetallic Compound with Dense Au20 and Open AuSn4 Layers," Inorg. Chem., 2009, 48, 11108-11113.
  4. Thimmaiah, S.; Weber, J.; Miller, G.J., "Vacancies and Insertions in the RE10Ni9+xIn20 Series (RE = Ho-Tm, Lu)," Z. Anorg. Allg. Chem.2009, 635, 1831-1839.
  5. Misra, S.; Mozharivskyj, Y.; Tsokol, A.O.; Schlagel, D.L.; Lograsso, T.A.; Miller, G.J., "Structural, Magnetic, and Thermal Characteristics of the Phase Transitions in Gd5GaxGe4-x Magnetocaloric Materials," J. Solid State Chem.2009, 182, 3031-3040.
  6. You, T.-S.; Zhao, J.-T.; Pöttgen, R.; Schnelle, W.; Burkhardt, U.; Grin, Y.; Miller, G. J., "Structure-composition sensitivity in 'Metallic' Zintl phases: A study of Eu(Ga1-xTtx)2 (Tt = Si, Ge, 0 < x < 1), J. Solid State Chem.2009, 182, 2430-2442.
  7. Gourdon, O.; Izaola, Z.; Elcoro, L.; Petricék, V.; Miller, G. J. "Structure Determination of Two Modulated γ-Brass Structures in the Zn-Pd System through a (3 + 1)-Dimensional Space Description," Inorg. Chem. 2009, 48, 9715-9722.
  8. Burghaus, J.; Dronskowski, R.; Miller, G.J., "Slater-Pauling Behavior within Quaternary Intermetallic Borides of the Ti3Co5B2 Structure Type," J. Solid State Chem.2009, 182, 2613-2619.
  9. Z. Qian, L. S. Chumbley, S. Misra, G. Miller, V. K. Pecharsky, K. A. Gschneidner, K. Ahn, A. S. Chernyshov and N. K. Singh "Electron microscopy examination of R5T4 alloys, where R = Ho, Yb and Gd, and T = Si, Ge, Ga and Sb," Acta Materialia, 2009, 57, 3374-3381.
  10. You, T.-S.; Miller, G. J. "Theoretical Interpretation of the Structural Variations along the Eu(Zn1-xGex)2 (0 < x < 1) Series," Inorg. Chem. 2009, 48, 6391-6401.
  11. You, T.-S.; Lidin, S.; Gourdon, O.; Wu, Y.; Miller, G. J., "To What Extent Does the Zintl-Klemm Formalism Work? The Eu(Zn1-xGex)2 Series," Inorg. Chem.2009, 48, 6380-6390.
  12. Li, B.; Kim, S.-J.; Miller, G. J.; Corbett, J. D., " Gold Tetrahedra as Building Blocks in K3Au5Tr (Tr = In, Tl) and Rb2Au3Tl and in Other Compounds: A Broad Group of Electron-Poor Intermetallic Phases," Inorg. Chem. 2009, 48, 6573-6583.
  13. Gupta, S.; León-Escamilla, E. A.; Miller, G.J.; Corbett, J.D., " R5Pn3-type Phases of the Heavier Trivalent Rare-Earth Metal Pnictides (Pn = Sb, Bi): New Phase Transitions for Er5Sb3 and Tm5Sb3," Inorg. Chem., 2009, 48, 4362-4371.
  14. Misra, S.; Miller, G.J., "Gadolinium Scandium Germanide, Gd2Sc3Ge4," Acta Cryst. Section E, 2009, E65, i25.
  15. Misra, S.; Poweleit, E.T.; Miller, G.J., "On the Crystal Structure, Metal Atom Site Preferences and Magnetic Properties of Nd5-xErxTt4 (Tt = Si or Ge)," Z. Anorg. Allg. Chem., 2009, 635, 889-897.
  16. Svitlyk, V.; Miller, G.J.; Mozharivskyj, Y. "Gd5Si4-xPx: Targeted Structural Changes through Increase in Valence Electron Concentration," J. Am. Chem. Soc., 2009, 131, 2367-2374.
  17. Wang, F.; Pearson, K.N.; Miller, G.J. "EuAgxAl11-x with the BaCd11-Type Structure: Phase Width, Coloring, and Electronic Structure," Chem. Mater., 2009, 21, 230-236.
  18. Davis, B. K.; Torikachvili, M. S.; Mun, E. D.; Frederick, J. C.; Miller, G. J.; Thimmaiah, S.; Bud'ko, S. L.; Canfield, P. C., "Hydrostatic pressure study of single-crystalline UNi0.5Sb2," J. Appl. Phys.2008, 103, 07B704/1-3.
  19. You, T.-S.; Han, M.-K.; Miller, G.J., "Phase Width and Site Preferences in the EuMgxGa4-x Series," Z. Anorg. Allg. Chem. (Special Issue dedicated to Dr. Hanke), 2008, 634, 2845-2852.
  20. Misra, S.; Miller, G. J., "Gd5-xYxTt4 (Tt = Si or Ge): Effect of Metal Substitution on Structure, Bonding, and Magnetism," J. Am. Chem. Soc., 2008, 130, 13900-13911.
  21. Samolyuk, G.; Miller, G. J. "Relation Between Chemical Bonding and Exchange Coupling Approaches to the Description of Ordering in Itinerant Magnets," special issue on "Computational Solid State Chemistry," J. Computational Chem., 2008, 29, 2177-2186.
  22. Jia, S.; Ni, N.; Samolyuk, G. D.; Safa-Sefat, A.; Dennis, K.; Ko, H.; Miller, G. J.; Bud'ko, S. L.; Canfield, P. C. "Variation of the magnetic ordering in GdT2Zn20 (T = Fe, Ru, Is, Co, Rh, and Ir) and its correlation with the electronic structure of isostructural YT2Zn20, Phys. Rev. B, 2008, 77, 104408/1-14.
  23. You, T.-S.; Han, M.-K.; Miller, G.J., "On the Coloring Problem in YMgZn and Related Phases," Inorg. Chim. Acta (Special Issue dedicated to Bob Angelici), 2008, 361, 3053-3062 .
  24. Fokwa, B.P.T.; Samolyuk, G.D.; Miller, G. J.; Dronskowski, R., "Ladders of a Magnetically Active Element in the Structure of the Novel, Complex Boride, Ti9Fe2Ru18B8: Synthesis, Structure, Bonding and Magnetism," Inorg. Chem., 2008, 47, 2113-2120.
  25. Han, M.-K, Miller, G.J., "An Application of the 'Coloring Problem:' Structure-Composition-Bonding Relationships in the Magnetocaloric Materials LaFe13-xSix," Inorg. Chem. 2008, 47(2), 515-528.
  26. You, Tae-Soo; Miller, G.J., "Planar vs. Puckered Nets in the Polar Intermetallic Series EuGaTt (Tt = Si, Ge, Sn)," Inorg. Chem. 2007, 46(21), 8801-8811.
  27. Samolyuk, G.; Fokwa, B. P. T.; Dronskowski, R.; Miller, G.J., " Electronic Structure, Chemical Bonding and Magnetic Properties in the Intermetallic Series Sc2Fe(Ru1-xRhx)5B2 from First Principles," Phys. Rev. B 2007, 76, 094404/1-12.
  28. Gourdon, O.; Gout, D.; Williams, D.J.; Proffen, T.; Hobbs, S.; Miller, G.J. "Atomic Distributions in the g-Brass Structure of the Cu-Zn System: A Structural and Theoretical Study," Inorg. Chem. 2007, 46, 251-260.
  29. Miller, G.J., "The Coloring Problem in Solids: Implications for Structures and Properties," Z. Anorg. Allg. Chem. 2006, 632, 2078.
  30. Miller, G.J. Review on Computational Chemistry of Solid State Materials, Angew. Chem. 2006, 45, 6785-6786.
  31. Han, M.-K.; Wu, Y.-Q.; Kramer, M.; Vatovez, B.; Grandjean, F.; Long, G. J.; Miller, G. J., "Superstructure in RE2-xFe4Si14-y (RE = Y, Gd-Lu) Characterized by Diffraction, Electron Microscopy and Mössbauer Spectroscopy," Inorg. Chem. 2006, 45, 10503-10519.
  32. Erickson, A. S.; Misra, S.; Miller, G. J.; Gupta, R. J.; Schlesinger, Z.; Harrison, W. A.; Fisher, I. R., "Ferromagnetism in the Mott Insulator Ba2NaOsO6," Phys. Rev. Lett. 2007, 99(1), 016404/1-4 .
  33. Misra, S. and Miller, G. J., "On the Distribution of Tetrelide Atoms (Si, Ge) in Gd5(SixGe1-x)4," J. Solid State Chem. 2006, 179, 2290-2297.
  34. Miller, G.J. "Magnetochemistry," 10 th Edition of McGraw-Hill Encyclopedia of Science & Technology, McGraw-Hill, New York, 2007, vol. 10, 323-327.
  35. Miller, G.J., "Rare-Earth Tetrelides, RE5(Si, Ge)4: Materials for Magnetic Refrigeration," Chem. Soc. Rev. 2006, 35, 799-813.
  36. Gourdon, O. and Miller, G. J., "Intergrowth Compounds in the Zn-rich Zn-Pd System: Towards 1D Quasicrystal Approximants," Chem. Mater., 2006, 18, 1848-1856 .
  37. Mozharivskyj, Y., Tsokol, A. O., Miller, G. J., "Structural Variations in Gd5Si4-xSnx: Size vs. Electronic Effects," Z. Kristallogr., 2006, 221, 493-501.
  38. Mozharivskyj, Y., Janssen, Y., Harringa, J. L., Kracher, A., Tsokol, A. O., Miller, G. J., "Zn13Sb10: A Structural and Landau Theoretical Analysis of Its Phase Transitions," Chem. Mater., 2006, 18, 822-831 .
  39. Gourdon, O., Izaola, Z., Elcoro, L., Petricek, V., Miller, G. J., "Zn1-xPdx (x = 0.14 to 0.24): A Missing Link between Intergrowth Compounds and Quasicrystal Approximants," Philos. Mag., 2006, 86, 419-425.


  1. Gemmill, W.R., Smith, M.D., Mozharivsky, Y.A., Miller, G. J., zur Loye, H.-C., "Crystal Growth, Structural Transitions and Magnetic Properties of the Fluorite-Related Osmates: Sm3OsO7, Eu3OsO7, and Gd3OsO7," Inorg. Chem., 2005, 44, 7047-7055.
  2. Gout, D., Barker, T.J., Gourdon, O., Miller, G. J., "A New Superstructure for the BaAl4-Structure Type: An Experimental and Theoretical Study of La2NiAl7," Chem. Mater., 2005, 17, 3661-3667.
  3. Gourdon, O., Gout, D., Miller, G.J., "Electronic States of Intermetallic Compounds," in Encyclopedia of Condensed Matter Physics, Eds. G. Bassani, G. Liedl, P. Wyder, Elsevier, Amsterdam, Netherlands, 2005, pp. 409-422.
  4. Mozharivskyj, Y.; Pecharsky, A.O.; Pecharsky, V.K.; Miller, G.J., "On the High-Temperature Phase Transition of Gd5Si2Ge2," J. Am. Chem. Soc., 2005, 127, 317-324.
  5. Han, M.-K.; Morosan, E.; Canfield, P.C.; Miller, G.J., "The Coloring Problem in Intermetallics: Bonding and Properties of Tb3Zn3.6Al7.4 with the La3Al11 Structure Type," Z. Kristallogr., 2005, 220(1), 1-7.
  6. Sebastian, S. E.; Yin, D.; Tanedo, P.; Jorge, G. A.; Harrison, N.; Jaime, M.; Mozharivskyj, Y.; Miller, G.; Krzystek, J.; Zvyagin, S. A.; Fisher, I. R. "High field behavior of the spin gap compound Sr2Cu(BO3)2," Los Alamos National Laboratory, Preprint Archive, Condensed Matter, 2004.
  7. Bobev, S.; Bauer, E. D.; Thompson, J. D.; Sarrao, J. L.; Miller, G. J.; Eck, B.; Dronskowski, R. "Metallic Behavior of the Zintl Phase EuGe2: Combined Structural Studies, Property Measurements and Electronic Structure Calculations," J. Solid State Chem., 2004, 177(10), 3545-3552.
  8. Gout, D.; Benbow, E.; Gourdon, O.; Miller, G. J., "Composition-Structure Relationships in Polar Intermetallics: Experimental and Theoretical Studies of LaNi1+xAl6-x (x = 0.44)," Inorg. Chem., 2004, 43, 4604-4609.
  9. Avila, M. A.; Wu, Y. Q.; Condron, C. L.; Bud'ko, S. L.; Kramer, M.; Miller, G. J.; Canfield, P. C. "Anomalous temperature-dependent transport in YbNi2B2C and its correlation to microstructural features," Phys. Rev. B, 2004, 69, 205107/1-7.
  10. Mozharivskyj, Y.; Pecharsky, A. O.; Pecharsky, V. K.; Miller, G. J.; Gschneidner, K. A., Jr. "Tracking and understanding the first-order structural transition in Er5Si4," Phys. Rev. B, 2004, 69, 144102/1-13.
  11. Mozharivskyj, Yu.; Pecharsky, A. O.; Bud'ko, S. L; Miller, G. J. "A Promising Thermoelectric Material: Zn4Sb3 or Zn6-dSb5. Its Composition, Structure, Stability, and Polymorphs. Structure and Stability of Zn1-dSb," Chem. Mater., 2004, 16, 1580-1589.
  12. Gourdon, O.; Bud'ko, S. L.; Williams, D.; Miller, G. J. "Crystallographic, Electronic and Magnetic Studies of z2-GaM (M = Cr, Mn, or Fe): From Antiferromagnetism to Ferromagnetism," Inorg. Chem., 2004, 43, 3210-3218.
  13. Petrovic, C.; Kim, J. W.; Bud'ko, S. L.; Goldman, A. I.; Canfield, P. C.; Choe, W.; Miller, G. J. "Anisotropy and large magnetoresistance in the narrow-gap semiconductor FeSb2," Phys. Rev. B: Cond. Matter Mater. Phys. 2003, 67(15), 155205/1-4.
  14. Pecharsky, V. K.; Pecharsky, A. O.; Mozharivskyj, Y.; Gschneidner, K. A., Jr.; Miller, G. J. "Decoupling of the Magnetic and Structural Transformations in Er5Si4," Phys. Rev. Lett. 2003, 91, 207205/1-4.
  15. Mozharivskyj, Yu.; Choe, W.; Pecharsky, A. O.; Miller, G. J. "Phase Transformation Driven by Valence Electron Concentration: Tuning Interslab Bond Distances in Gd5GaxGe4-x," J. Am. Chem. Soc. 2003, 125, 15183-15190.
  16. Choe, W.; Pecharsky, A. O.; Wörle, M.; Miller, G. J. " 'Nanoscale Zippers' in Gd5(SixGe1-x)4: Symmetry and Chemical Influences on the Nanoscale Zipping Action," Inorg. Chem. 2003, 42, 8223-8229.
  17. Condron, C. L.; Miller, G. J.; Strand, J. D.; Bud'ko, S. L.; Canfield, P. C. "A New Look at Bonding in Trialuminides: Reinvestigation of TaAl3," Inorg. Chem. 2003, 42, 8371-8376.
  18. Condron, C. L.; Strand, J. D.; Canfield, P.; Miller, G. J. "The intermetallic compound Gd6Ta4Al43," Acta Crystallogr, Sect. E: Structure Reports Online 2003, E59, i147-i148.
  19. Pecharsky, A. O.; Mozharivskyj, Yu.; Dennis, K. W.; Gschneidner, Jr., K. A.; McCallum, R. W.; Miller, G. J.; Pecharsky, V. K. "Preparation, crystal structure, heat capacity, magnetism, and the magnetocaloric effect of Pr5Ni1.9Si3 and PrNi," Phys. Rev. B 2003, 68, 134452/1-8.
  20. Gout, D.; Benbow, E.; Gourdon, O.; Miller, G. J. "Theoretical studies on cerium nickel aluminides: polar intermetallics with heavy fermion behavior," J. Solid State Chem. 2003, 176, 538-548.
  21. Smith, M. D.; Miller, G. J. "Synthesis and Structure of Ta4SI11: Disorder and Mixed-Valency in the First Tantalum Sulfide Iodide," Inorg. Chem. 2003, 42, 4165-4170.
  22. Choe, W.; Miller, G. J.; Meyers, J.; Chumbley, S.; Pecharsky, A. O. "Nanoscale Zipper in the Crystalline Solid: How the Nanoscale Zipping Action Can Create Structural Variations in the Magnetocaloric Material Gd5(Si1.5Ge2.5)," Chem. Mater. 2003, 15, 1413-1419.
  23. Gout, D.; Benbow, E.; Gourdon, O.; Miller, G. J. "Crystallographic, Electronic and Magnetic Studies of Ce4Ni6Al23: A New Ternary Intermetallic Compound in the Aluminum-Cerium-Nickel Phase Diagram," J. Solid State Chem. 2003, 174, 471-481.
  24. Lee, C.-S.; Miller, G. J. "Ba14Zn5-xAl22+x: A New Polar Intermetallic Compound with a Novel 2D Network," J. Solid State Chem. 2003, 170, 94-105.
  25. Gourdon, O.; Miller, G. J. "Reinvestigation of the GaMn Structure and Theoretical Studies of Its Electronic and Magnetic Properties," J. Solid State Chem. 2003, 173, 137-147.
  26. Kang, S. K.; Miller, G. J. "The intermetallic compound BaAgBi," Acta Crystallogr, Sect. E: Structure Reports Online 2002, E58, i21-i22.
  27. Lee, E. K.; Miller, G. J.; Kang, S. K. "The intermetallic compound BaAuSb," Acta Crystallogr, Sect. E: Structure Reports Online 2002, E58, i17-i18.
  28. Gout, D.; Benbow, E.; Miller, G. J. "Structure and Bonding Consequences in the Pseudo-Binary System Ln5Si3-xMx (Ln = La, Ce or Nd; M = Ni, Co)," J. Alloys Comp. 2002, 338, 153-164.
  29. Choe, W.; McWhorter, S.; Miller, G. J. "Gd2AlGe2: An "Almost-Zintl Phase" and a New Stacking Variant of the W2CoB2 Type," Z. anorg. allg. Chem. 2002, 628, 1575-1580.
  30. Miller, G. J.; Verkade, J. G. "Shell Structures in Molecular Orbital Energy Diagrams for "Small" Fullerene Cages: Free-Electron vs. Generator Orbital Models," J. Math. Chem. 2003, 33, 55-79.
  31. Meyer, J.; Chumbley, S.; Choe, W.; Miller, G. J. "A Microstructural Analysis of Twinned b-Gd5Si2Ge2," Phys. Rev. B: Condens. Mat. Mat. Phys. 2002, 66, 012106/1-3.
  32. Häussermann, U.; Amerioun, S.; Eriksson, L.; Lee, C.-S.; Miller, G. J. "The s-p Bonded Representatives of the Prominent BaAl4 Structure Type: A Case Study on Structural Stability of Polar Intermetallic Network Structures," J. Am. Chem. Soc. 2002, 124, 4371-4383.
  33. Levin, E. M.; Pecharsky, V. K.; Gschneidner, Jr., K.A.; Miller, G. J. "The Electrical Resistivity, Electronic Heat Capacity and Electronic Structure of Gd5Ge4," Phys. Rev. B: Condens. Mat. Mat. Phys. 2001, 64, 235103/1-11.
  34. Choe, W.; Levin, E.M.; Miller, G. J. "Crystal Structure and Magnetism of Gd2MgGe2," J. Alloys Comp. 2001, 329, 121-130.
  35. Lee, C.-S.; Miller, G. J. "Li10Mg6Zn31Al3: A New Intermetallic Phase Containing Building Blocks for Decagonal Quasicrystals," Angew. Chem. Int. Ed. 2001, 40, 4740-4742; Angew. Chem. 2001, 113, 4876-4878.
  36. Miller, G. J.; Lee, C.-S.; Choe, W. "Structure and Bonding Around the Zintl Border," Highlights in Inorganic Chemistry, Ed. G. Meyer, Wiley-VCH, 2002, 21-54.
  37. Miller, G. J.; Lee, C.-S.; Tsai, W.-J. "Where are the Atoms in Quasicrystals? Experimental and Theoretical Studies of Ternary and Quaternary Approximants," Mat. Res. Soc. Proc. 2001, 643, K3.1.1-11.


  1. Lee, C.-S.; Miller, G. J. "Experimental and Theoretical Studies of Elemental Site Preferences in Quasicrystalline Approximants (R-Phases) within the Li-Mg-Zn-Al System," Inorg. Chem., 2000, 40, 338-345.
  2. Choe, W.; Pecharsky, V.K.; Gschneidner,K.A., Jr.; Young, V.G., Jr.; Miller, G. J. "Making and Breaking Covalent Bonds Across the Magnetic Transition in the Giant Magnetocaloric Material, Gd5(Si2Ge2)," Phys. Rev. Lett., 2000, 84(20), 4617-4620.
  3. Lee, C.-S.; Miller, G. J. "Where Are The Elements in Complex Aluminides? An Experimental and Theoretical Investigation of the Quasicrystalline Approximants Mg2-y(ZnxAl1-x)3+y," J. Am. Chem. Soc., 2000, 122, 4937-4947.
  4. Smith, M.D.; Miller, G. J. "Tantalum-Niobium Mixing in Ta3-xNbxTeI7 (0 £ x £ 3)," Z. Anorg. Allg. Chem., 2000, 626, 94-102.
  5. -S.; Miller, G. J. "Vacancy Ordering and Bonding Competition in Group 9 Tellurides, MxTe2 (M = Rh, Ir; 0.75 £ x £ 2): A Theoretical Study," Inorg. Chem., 1999, 38, 5139-5150.
  6. Miller, G. J.; Heideman, S.A.; Greenbowe, T.J. "Introducing Proper Chemical Hygiene and Safety in the General Chemistry Curriculum," J. Chem. Educ., 2000, 77(9), 1185-1187.
  7. K.; Miller, G. J. "The Crystal Structure of Ta5Sb4," Acta Cryst., Sect C, 1999, C55, 483-485.
  8. Nordell, K. J.; Miller, G. J. "Linking Intermetallics and Zintl Compounds: An Investigation of Ternary Trielides (Al, Ga, In) Forming the NaZn13 Structure Type," Inorg. Chem., 1999, 38, 579-590.
  9. Zavaliy, I. Yu.; Pecharsky, V. K.; Miller, G. J.; Akselrud, L. G. "Hydrogenation of Zr6MeX2 Intermetallic Compounds (Me = Fe, Co, Ni; X = Al, Ga, Sn): Crystallographic and Theoretical Analysis," J. Alloys Comp., 1999, 283, 106-116.
  10. Miller, G. J.; Verkade, J. G. "A Pictorial Approach to Bonding in Polymers," J. Chem. Educ., 1999, 76, 428-434.
  11. Smith, M. D.; Miller, G. J. "Polytypism in the Nb3TeI7 System," J. Alloys Comp., 1998, 281, 202-205.
  12. Smith, M. D. and Miller, G. J. "Ta3SBr7-A New Structure Type in the M3QX7 Family (M = Nb, Ta; Q = S, Se, Te; X = Cl, Br, I)," J. Solid State Chem., 1998, 140, 226-232.
  13. D.; Miller, G. J. "Hexamolybdenum Octatelluride, Mo6Te8," Acta Cryst., Sect. C, 1998, C54, 709-710.
  14. Miller, G. J. "The Coloring Problem in Solids: How It Affects Structure, Composition and Properties," Eur. J. Inorg. Chem., 1998, 523-536.
  15. Miller, G. J. "Safety in the Chemistry Curriculum at Iowa State University," in Educating the OSHA Savvy Chemist, ACS Symposium Series No. 700, P. Utterback and D. Nelson, Eds., American Chemical Society, 1998, Chapter 10.
  16. Miller, G. J.; Smith, M. D.; Wang, M.; Wang, J. "The Synthesis and Crystal Structure of Rb4TmI6: Lattice Energy Calculation on Network of Condensed Cubes," J. Alloys Comp., 1998, 265, 140-145.
  17. Vaughey, J. T.; Miller, G. J.; Gravelle, S.; Leon-Escamilla, E. A.; Corbett, J. D. "Synthesis, Structure, and Properties of BaGe2: A Study of Tetrahedral Cluster Packing and Other Three-Connected Nets in Zintl Phases," J. Solid State Chem., 1997, 133, 501-507.
  18. Nordell, K. J.; Miller, G. J. "Ln3Au2Al9 (Ln = Dy, Tb): Heteronuclear vs. Homonuclear Bonding in Intermetallics," Angew. Chem., 1997, 109, 2098-2101.
  19. ; Young, V. G.; Miller, G. J. "A Bioctahedral Nb(IV) Cluster with Bridging Sulfides: Nb2(h-S)2Cl4(thf)4," Acta Cryst., Sect. C, 1997, C53, 1041-1043.
  20. Young, D. M.; Charlton, J.; Olmstead, M. M.; Kauzlarich, S. M.; Lee, C.-S.; Miller, G. J. "BaCu10P4: A New Structure Composed of Chains of Edge-Shared Cu4 Tetrahedra," Inorg. Chem., 1997, 36, 2539-2543.
  21. Book Chapters: Ch. 13 ("Polymers") and Ch. 14 ("Clusters and Cages") in A Pictorial Approach to Molecular Bonding, 2nd Ed., by J.G. Verkade, Springer-Verlag, 1996.
  22. Smith, M. D.; Miller, G. J. "Novel Tantalum Chalcogenide Halides: The First Ta3 Clusters in the Solid State," J. Am. Chem. Soc., 1996, 118, 12238-12239.
  23. Nordell, K. J.; Miller, G. J. "Electronic Structure, Superconductivity, and Substitution Patterns in Tl5Te3," J. Alloys Comp., 1996, 241, 51-62.
  24. Miller, G. J. "Structure and Bonding at the Zintl Border," in Chemistry, Structure, and Bonding of Zintl Phases and Ions, Ed., S. M. Kauzlarich, VCH Publishers, New York: 1996, pp. 1-59.
  25. Miller, G. J. "Orbital Symmetry and Superconductivity in Carbides and Borocarbides," in Transition Metal Carbides and Nitrides, Ed., S. Ted Oyama, Chapman & Hall, New York: 1996, pp. 134-153.
  26. ; Lin, J.; Young, V. G.; Miller, G. J. "Synthesis, Structure, and Bonding in Nb2(h6-mesitylene)2(h-I)4 and a New Intermediate-Valent Dinuclear Niobium Complex, [Nb2(h6-mesitylene)2(h-I)4]I," J. Organometallic Chem., 1996, 507, 31-39.


  1. Nordell, K. J.; Miller, G. J. "BaCu5Al8: A Structure Containing Interconnected [Al8Cu5]2- Stuffed Icosahedra," Croat. Chem. Acta, 1995, 68, 825-835.
  2. Miller, G. J. "Chemistry and Properties of Novel Niobium Cluster Compounds," J. Alloys Comp., 1995, 229, 93-106.
  3. Miller, G. J.; Cheng, J. "Ternary Metal-Rich Phosphides: Structure, Bonding and Site Preferences in ZrNbP and Hf1+xMo1-xP," Inorg. Chem., 1995, 34, 2962-2968.
  4. J. "Solid State Chemistry of Nb3Cl8: Nb3TeCl7, Mixed Crystal Formation, and Intercalation," J. Alloys Comp., 1995, 217, 5-12.
  5. J. "On the Electronic Structure of the New "Intermetallics" LnNi2B2C," J. Am. Chem. Soc., 1994, 116, 6332-6336.
  6. Lin, J.; Miller, G. J. "The Structure of Na3SbTe3: How Ionic and Covalent Bonding Forces Work Together," J. Solid State Chem., 1994, 113, 296-302.
  7. Miller, G. J.; Lin, J. "Small Molecules Stabilized in Inorganic Framework: NbI5 Monomers in the Novel Layered Compound Nb7S2I19," Angew. Chem., 1994, 106, 357-359; Angew. Chem. Intl. Ed. Engl., 1994, 33, 334-336.
  8. Miller, G. J.; Deng, H.; Hoffmann, R. "Ternary Group VIII Hydrides: Ligand Field and Cation Orbital Effects in their Electronic Structures," Inorg. Chem., 1994, 33, 1330-1339.
  9. Mackey, R.; Miller, G. J.; Franzen, H. F. "New Oxides of the Filled Ti2Ni-Type Structure," J. Alloys Comp., 1994, 204, 109-118.
  10. Miller, G. J. "Solid State Halides: Structures and Properties," Encyclopedia of Inorganic Chemistry, Wiley-Interscience, London, 1994.
  11. Miller, G. J.; Lin, J.; Young, Jr., V. "Crystal Structure and Bonding in TaCl4(NC5H5)2," Acta Cryst., Sect. C, 1993, 49, 1770-1773.
  12. Nesper, R.; Miller, G. J. "A Covalent View of Chemical Bonding in Laves Phases CaLixAl2-x," J. Alloys Comp., 1993, 197, 109-121.
  13. Miller, G. J.; Li, F.; Franzen, H. F. "The Structural Phase Transition in CaAl4: A Concerted Application of Landau Theory and Energy Band Theory," J. Am. Chem. Soc., 1993, 115, 3739-3745.
  14. ; Miller, G. J. "Dimensional Diversity in Transition Metal Trihalides," Inorg. Chem., 1993, 32, 1476-1487.
  15. Yao, X.; Miller, G. J.; Franzen, H. F. "Crystal Structure and Electronic Structure of NbxTa2-xS (x = 0.95), A New Layered Compound in the Ternary Ta-Nb-S System," J. Alloys Comp., 1992, 183, 7-17.
  16. Michaelis, C.; Bauhofer, W.; Buchkremer-Hermanns, H.; Kremer, R. K.; Simon, A.; Miller, G. J. "LnHal2Hn-Neue Phasen in den ternären Systemen Ln/Hal/H (Ln = Lanthanoid, Hal = Br, I). III.: Physikalishe Eisenschaften," Z. anorg. allg. Chem., 1992, 618, 98-106.
  17. Miller, G. J.; Nesper, R. "Ca8-xLixAl3: Defects and Substitution in the Fe3Al Structure Type," J. Alloys Comp., 1992, 185, 221-234.
  18. Dronskowski, R.; Simon, A.; Miller, G. J. "Comment on the Existence of Phases AxMo5As4 with Ax = Al2, Ga2, Cu2, Cu4," J. Chem. Soc. Dalton Trans., 1991, 2483-2484.
  19. Simon, A.; Mattausch, Hj.; Miller, G. J.; Bauhofer, W.; Kremer, R. K. "Metal-Rich Halides of the Rare Earth Elements-Structure, Bonding, and Properties," Handbook of Physics and Chemistry of the Rare Earths, 1991, 15, 191-285.


  1. ; Mattausch, Hj.; Miller, G. J.; Bauhofer, W.; Kremer, R. K.; Simon, A. "Structur und Eigenschaften von Gd2XC (X = Cl, Br, I)," J. Less-Common Met., 1990, 167, 65-79.
  2. Burdett, J. K.; Miller, G. J. "The Fragment Formalism in Main Group Solids: Applications to AlB2, CaAl2Si2, BaAl4, and Related Materials," Chem. Mater., 1990, 2, 12-26.
  3. ; Köhler, J.; Tischtau, R.; Miller, G. J. "K4Al2Nb11O20F-'Missing Link' der Clusterkondensation," Angew. Chem., 1989, 101, 1695.
  4. Köhler, J.; Miller, G. J.; Simon, A. "Na(V3-xNbx)Nb6O14-ein neues Oxoniobat mit [Nb6O12]-, und [M2O9]-Cluster," Z. anorg. allg. Chem., 1988, 568, 8-21.
  5. Burdett, J. K.; Miller, G. J.; Richardson, Jr., J. W.; Smith, J. V. "Low-Temperature Neutron Powder Diffraction Study of CrO2 and the Validity of the Jahn-Teller Viewpoint," J. Am. Chem. Soc., 1988, 110, 8064-8071.
  6. ; Krebs, B.; Simon, A.; Miller, G. J.; Hettich, B. "Die Kristall und Molekülstruktur von Mangan(VII)-oxid," Z. anorg. allg. Chem., 1988, 558, 7-20.
  7. ; Miller, G. J.; Simon, A. "Preparation, Crystal Structures, and Electronic Properties of LiGaCl3 and LiGaI3," J. Solid State Chem., 1988, 75, 147-155.
  8. Reinen, D.; Allmann, R.; Baum, G.; Jakob, B.; Kaschuba, U.; Massa, W.; Miller, G. J. "Jahn-Teller-Verzerrungen von Übergangsmetallionen in tetraedrischer Koordination-die Strukturen von Cat[MII(NCS)4] (MII: Co, Ni, Cu) und von Spinellmischkristallen MIICr2O4 (MII: Zn-Ni, Zn-Cu, Cu-Ni)," Z. anorg. allg. Chem., 1987, 548, 7-21.
  9. Burdett, J. K.; Miller, G. J. "Interstitial Hydrogen in the Early-Transition-Metal Halides," J. Am. Chem. Soc., 1987, 109, 4092-4104.
  10. Burdett, J. K.; Miller, G. J. "Polyhedral Clusters in Solids: The Electronic Structure of Pentlandite," J. Am. Chem. Soc., 1987, 109, 4081-4091.
  11. K.; Hughbanks, T.; Miller, G. J.; Richardson, Jr., J. W.; Smith, J. V. "Structural-Electronic Relationships in Inorganic Solids: Powder Neutron Diffraction Studies of the Rutile and Anatase Polymorphs of Titanium Dioxide at 15 and 295 K," J. Am. Chem. Soc., 1987, 109, 3639-3646.
  12. J.; Burdett, J. K.; Schwarz, C.; Simon, A. "Molecular Interstitials: An Analysis of the Gd2C2Cl2 Structure," Inorg. Chem., 1986, 25, 4437-4444.
  13. Burdett, J. K.; Miller, G. J. "Electronic Control of the Structural Stability of Quasi-Periodic Linear Chains," Inorg. Chem., 1986, 25, 4069-4071.
  14. Burdett, J. K.; Canadell, E.; Miller, G. J. "Electronic Structure of Transition Metal Borides with the AlB2 Structure," J. Am. Chem. Soc., 1986, 108, 6561-6568.