College of Liberal Arts and Sciences

Department of Chemistry

Jesudoss Kingston

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Selected Publications

  1. Synthesis and characterization of R2PN=P(iBuNCH2CH2)3N: A new bulky electron-rich phosphine for efficient Pd-assisted Suzuki-Mityaura cross-coupling reactions.

    Jesudoss V. Kingston, John G. Verkade

    Journal of Organic Chemistry, 2007, 72, 2816.

  2. 3/2 Order chain kinetics involving a postulated dicationic intermediate in the isomerization of a P-isocyano to P-cyano azaphosphatrane monocation.

    Jesudoss V. Kingston, John G. Verkade, James H. Espenson

    Journal of the American Chemical Society, 2005,127, 15006.

  3. P[N(iBu)CH2CH2]3N: A versatile non-ionic base for the synthesis of higher coordinate silicates.

    Jesudoss V. Kingston, John, G. Verkade

    Inorganic Chemistry Communications, 2005, 8, 643.

  4. A stable structurally characterized phosphorus-bound isocyanide and its thermal and catalyzed isomerization to the corresponding cyanide.

    Jesudoss V. Kingston, Arkady Ellern, John, G. Verkade

    Angewandte Chemie International Edition, 2005, 44, 4960.

  5. Reductive coupling of [(RO)2Ti(L2)2] complexes containing a chelating bis(aryloxide ligand with ketones (L2 = bpy, dmbpy or phen). clear="none"/>
    David Owiny, Jesudoss V. Kingston, Mark Maynor, Sean Parkin, Jeff W. Kampf, Folami T. Ladipo

    Organometallics, 2005, 24, 3995.

  6. Dianionic silicate derivatives of transition metals: synthesis by a facile ion exchange route, characterization and thermolysis studies.

    P. Bindu, J.V. Kingston, M.N. Sudheendra Rao

    Polyhedron, 2004, 23, 679.

  7. Novel pentacoordinate siliconium complexes stabilized by oxygen and nitrogen donors: Highly sensitive and unusual equilibrium between ionic penta- and neutral hexacoordinate compounds.

    Inna Kalikhman, Vijeyakumar Kingston, Sonia Krivonos, Daniel Kost

    Organosilicon chemistry V, From Molecules to Materials, Eds.: N. Auner and J. Weis., VCH-Wiley, Weinheim, September 2003, 55.

  8. Binuclear ethylene bridged silicon chelates: Equilibrium between neutral hexacoordinate and ionic pentacoordinate siliconium complexes.

    Inna Kalikhman, Vijeyakumar Kingston, Daniel Kost

    Organoslilicon chemistry V, From Molelcules to Materials, Eds.: N. Auner and J. Weis., VCH-Wiley, Weinheim, September 2003, 61.

  9. Synthesis and reactivity of [(DMSC)Ti(2-OCAr2)L2] complexes (DMSC = Dimethylsilyl-bridged p-tert-butylcalix[4]arene dianion, Ar = Aryl Group, and L2 = Delocalized diimine).

    Jesudoss V. Kingston, Vallipuram Sarveswaran, Sean Parkin, Folami T. Ladipo

    Organometallics, 2003, 22, 136.

  10. Mechanistic insight into fragmentation reactions of titanapinacolate complexes.

    Jesudoss V. Kingston, Oleg V. Ozerov, Sean Parkin, Carolyn P. Brock, Folami T. Ladipo

    Journal of the American Chemical Society, 2002, 124, 12217.

  11. Donor-stabilized silyl cations. 5. Comparison between mono- and binuclear siliconium chelates.

    Inna Kalikhman, Vijeyakumar Kingston, Boris Gostevskii, Vadim Pestunovich, Dietmar Stalke, Bernard Walfort, Daniel Kost

    Organometallics, 2002, 21, 4468.

  12. Donor-stabilized silyl cations. 3. Ionic dissociation of hexacoordinate silicon complexes to pentacoordinate siliconium salts driven by ion solvation.

    Daniel Kost, Vijeyakumar Kingston, Boris Gostevskii, Arkady Ellern, Dietmar Stalke, Bernard Walfort, Inna Kalikhman

    Organometallics, 2002, 21, 2293.

  13. Low-temperature ionization of neutral hexacoordinate to ionic pentacoordinate silicon complexes: Unusual temperature, solvent and substituent effects.

    Daniel Kost, Inna Kalikhman, Vijeyakumar Kingston, Boris Gostevskii.

    Journal of Physical Organic Chemistry, 2002, 15, 831.

  14. Neutral hexacoordinate silicon tris-chelates: Structure and stereodynamics.

    Inna Kalikhman, Vijeyakumar Kingston, Olga Girshberg, Daniel Kost

    Organometallics, 2001, 20, 4713.

  15. Equilibrium between neutral hexacoordinate silicon complexes and ionic pentacoordinate siliconium salts through fast dissociation-recombination of the Si-Cl bond.

    Vijeyakumar Kingston, Boris Gostevskii, Inna Kalikhman, Daniel Kost

    Journal of Chemical Society, Chemical Communications, 2001, 14, 1272.

  16. Synthesis and characterization of tris(catecholato) silicates, [(C6H4O2)3Si]2 with different counter cations - First pyrolysis study and X-ray structure of [{(CH3)2CH}2NH2 ]2-[(C6H4O2)3Si].2CH3CN.H 2O.

    J.V. Kingston, Babu Vargheese, M.N. Sudheendra Rao

    Main Group Chem., 2000, 3, 79-90.

  17. High yield synthesis of cyclic phosphites, phosphates, sulphites and sulphates of catechol and glycol mediated by hypervalent silicon centers.

    J.V. Kingston, M.N. Sudheendra Rao

    Tetrahedron Letters, 1997, 38, 4841.