College of Liberal Arts and Sciences

Department of Chemistry

Aaron D. Sadow

Organometallic Chemistry and Asymmetric Catalysis

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Selected Publications

  1. Sadow, A. D.; Tilley, T. D., "Synthesis and Characterization of Scandium Silyl Complexes. σ-Bond Metathesis Reactions of Cp*2Sc Complexes and Catalytic Hydrocarbon Functionalizations via Dehydrogenative Silation." J. Am. Chem. Soc. 2005, 127, 643.

  2. Sadow, A. D.; Haller, I,; Fadini, L.; Togni, A. "Nickel(II)-Catalyzed Highly Enantioselective Hydrophosphination of Methacrylonitrile." J. Am. Chem. Soc. 2004, 126, 14704.

  3. Sadow, A. D.; Tilley, T. D., "Enhanced Reactivity of Cationic Hafnocene Complexes towards σ-Bond Metathesis Reactions. Si-H and Si-C Bond Activations in Stoichiometric and Catalytic Organosilane Conversions." Organometallics 2003, 22, 3577.

  4. Sadow, A. D.; Tilley, T. D., "Cationic Hafnium Silyl Complexes and their Enhanced Reactivity in σ-Bond Metathesis Processes with Si-H and C-H Bonds." J. Am. Chem. Soc. 2003, 125, 9462.

  5. Sadow, A. D.; Tilley, T. D., "Activation of Methane by σ-Bond Metathesis with (η5-C5Me5)2ScCH2CMe3. The Possible Role of Nondegenerate Alkyl Exchange in a Catalytic Hydromethylation of Propene." J. Am. Chem. Soc. 2003, 125, 7971.

  6. Sadow, A. D.; Tilley, T. D., "Catalytic Functionalization of Hydrocarbons via σ-Bond Metathesis Chemistry: Dehydrosilation of Methane with a Scandium Catalyst." Angew. Chem. Int. Ed. Engl. 2003, 42, 803-805.

  7. Sadow, A. D.; Tilley, T. D., "Activation of Arene C-H Bonds by a Cationic Hafnium Silyl Complex Possessing an Α-Agostic Si-H Interaction." J. Am. Chem. Soc. 2002, 124, 4457-4459.

  8. Sadow, A. D.; Tilley, T. D., "Enhanced Reactivity of Cationic vs. Neutral Hafnocene Complexes in Stoichiometric and Catalytic σ-bond Metathesis Reactions Involving Si-H and Si-C Bonds." Organometallics, 2001, 20, 4457-4459.

  9. Pawlow, J. H.; Sadow, A. D.; Sen, A., "Palladium (II)-Catalyzed Terpolymerization of Alkane-Α,ω-dinitrite Esters, Alkenes, and Carbon Monoxide to Polysuccinates." Organometallics, 1997, 16, 5659-5663.

  10. Pawlow, J. H.; Sadow, A. D.; Sen, A., "Palladium (II) Catalyzed Carbonylation of Alkane Dinitrite Ester to Polyoxalates." Organometallics, 1997, 16, 1339-1342.